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Phosphorus desorption kinetics in relation to phosphorus forms and sorption properties of Portuguese acid soils

dc.contributor.authorMonteiro, M.C.H.
dc.contributor.authorTorrent, J.
dc.date.accessioned2010-05-10T15:30:17Z
dc.date.available2010-05-10T15:30:17Z
dc.date.issued2007
dc.descriptionO artigo não está disponível em livre acesso. Pode ser solicitado através do site do editor.pt
dc.description.abstractWhile much information exists on the quantitative relationships between phosphorus (P) sorption and soil properties, comparatively less attention has been given to the influence of soil properties and P forms on the kinetics of P desorption, and to the relationships between desorbable and sorbed P. The aim of this study was to rationalize the P desorption properties of a group of 29 acid soils representative of agricultural areas of Portugal. The soils differed widely in basic properties, total P concentration (91-1730 mg kg-1), Olsen P (2.5-116 mg kg-1), and relative contents of the ‘P fractions’ —defined operationally in accordance with the seven-step fractionation scheme of Ruiz et al. (1997). P sorption capacity was accurately predicted from the concentrations of oxalate-extractable Al and Fe, as is generally the case with acid soils. Desorption of sorbed P to an anion exchange resin could be described by a combination of two kinetic equations of the Michaelis-Menten type for fast and slowly desorbable P pools. Although the concentrations of both pools were correlated with those of various P fractions, they could not be unambiguously assigned to specific chemical P species. The high correlation found between fast desorbable P and Olsen P testifies to the usefulness of this agricultural P test for acid soils; however, Olsen P tended to overestimate and underestimate fast desorbable P for Olsen P values below and above ~80 mg kg-1, respectively. The average ratio of fast desorbable P to sorbed P was 0.21 and that of total desorbable P to sorbed P 0.60; both ratios increased with increasing degree of P saturation in the soil.pt
dc.identifier.citationMONTEIRO, M.C.H. and TORRENT, J. (2007). Phosphorus desorption kinetics in relation to phosphorus forms and sorption properties of Portuguese acid soils. Soil Science. 172(8):631-638pt
dc.identifier.issn0038-075X
dc.identifier.urihttp://hdl.handle.net/10400.11/193
dc.language.isoengpt
dc.publisherLippincott Williams & Wilkinspt
dc.subjectPhosphorus desorptionpt
dc.subjectPhosphorus sorptionpt
dc.subjectAcid soilspt
dc.subjectOlsen Ppt
dc.titlePhosphorus desorption kinetics in relation to phosphorus forms and sorption properties of Portuguese acid soilspt
dc.typejournal article
dspace.entity.typePublication
oaire.citation.endPage638pt
oaire.citation.startPage631pt
oaire.citation.titleSoil Sciencept
person.familyNameMonteiro
person.givenNameM.C.H.
person.identifier.ciencia-id5D12-6B5C-23F1
person.identifier.orcid0000-0003-0101-1599
rcaap.rightsrestrictedAccesspt
rcaap.typearticlept
relation.isAuthorOfPublication00f17bad-649e-4953-a3a4-dd8c48b67f05
relation.isAuthorOfPublication.latestForDiscovery00f17bad-649e-4953-a3a4-dd8c48b67f05

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